N-(4-Chloro-2-nitrophenyl)-N-(methylsulfonyl)acetamide
نویسندگان
چکیده
The title compound, C(9)H(9)ClN(2)O(5)S, is of inter-est as a precursor to biologically active substituted quinolines and related compounds. The structure displays inter-molecular C-H⋯O inter-actions. Each mol-ecule is linked to two adjacent neighbours via weak centrosymmetric dimer-forming inter-actions, forming chains in the [101] direction.
منابع مشابه
N-(4-Methoxy-2-nitrophenyl)-N-(methylsulfonyl)acetamide
In the title compound, C(10)H(12)N(2)O(6)S, the nitro group is twisted slightly out of the plane of the aromatic ring, forming a dihedral angle of 20.79 (1)°. In the crystal, the mol-ecules arrange themselves as a chain along the a axis through inter-molecular C-H⋯O inter-actions.
متن کامل2,2-Dichloro-N-(3-nitrophenyl)acetamide
The conformation of the N-H bond in the structure of the title compound (3NPDCA), C(8)H(6)Cl(2)N(2)O(3), is anti to the meta-nitro group, similar to that in the structures of 2-chloro-N-(3-nitro-phen-yl)acetamide (3NPCA) and 2,2,2-trichloro-N-(3-nitro-phen-yl)acetamide (3NPTCA), and the meta-chloro group in 2,2-dichloro-N-(3-chloro-phen-yl)acetamide (3CPDCA). The geometric parameters of 3NPDCA ...
متن کاملN-(4-Methoxy-2-nitrophenyl)-N-(methylsulfonyl)methanesulfonamide
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متن کامل2-Chloro-N-(3-methylphenyl)acetamide
The conformation of the N-H bond in the structure of the title compound, C(9)H(10)ClNO, is syn to the meta-methyl group, in contrast to the anti conformation observed with respect to the meta-nitro group in 2-chloro-N-(3-nitro-phen-yl)-acetamide. The asymmetric unit of the title compound contains two mol-ecules. The geometric parameters of the title compound are similar to those of 2-chloro-N-(...
متن کاملN-Benzyl-2-(3-chloro-4-hydroxyphenyl)acetamide
The title compound, C(15)H(14)ClNO(2), was synthesized as part of a project to generate a combinatorial library based on the fungal natural product 2-(3-chloro-4-hy-droxy-phen-yl)acetamide. It crystallizes as non-planar discrete mol-ecules [the peripheral 3-chloro-4-hy-droxy-phenyl and benzyl groups are twisted out of the plane of the central acetamide group, with N-C-C-C and C-C-C-C torsion an...
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008